Abstract
In order to produce an inexpensive catalyst for the Fischer–Tropsch synthesis (FTS), zeolitized high silicon fly ash utilized as a catalytic support for cobalt nanoparticles. The ability of this new support in proper hosting of nanoparticles studied through various characterization methods such as X-ray diffraction, nitrogen sorption, transmission electron microscopy, energy-dispersive spectroscopic and temperature-programmed reduction. In addition, the catalytic properties for the FTS evaluated at 523 K and 20 MPa. The obtained results show remarkable influence of utilized support specifications upon the formation and catalytic behavior of cobalt nanoparticles in the FTS.
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Schulz H (1999) Appl Catal A 186:3
Dry ME (2001) J Chem Technol Biotechnol 77:43
Gregor JH (1990) Catal Lett 7:317
Dry ME (2002) Catal Today 71:227
Li H, Li J, Ni H, Song D (2006) Catal Lett 110:71
Khodakov AY, Griboval-Constant A, Bechara R, Zholobenko VL (2002) J Catal 206:230
Riva R, Miesner H, Vitali R, Del Piero G (2000) Appl Catal A 196:111
Jacobs G, Das TK, Zhang Y, Li J, Racoillet G, Davis BH (2002) Appl Catal A 233:263
Ernst B, Libs A, Chaumette P, Kiennemann A (1999) Appl Catal A 186:145
Ohtsuka Y, Takahashi Y, Noguchi M, Arai T, Takasaki S, Tsubouchi N, Wang Y (2004) Catal Today 89:419
Panpranot J, Goodwin JG Jr, Sayari A (2002) Catal Today 77:269
Griboval-Constant A, Khodakov AY, Bechara R, Zholobenko VL (2002) Stud Surf Sci Catal 144:609
Khodakov AY, Bechara R, Griboval-Constant A (2002) Stud Surf Sci Catal 142:1133
Wang Y, Noguchi M, Takahashi Y, Ohtsuka Y (2001) Catal Today 68:3
Martínez A, López C, Márquez F, Díaz I (2003) J Catal 220:486
Suvato S, Pakkanen TA (2000) J Mol Catal A: Chem 164:273
Suzuki M, Tsutsumi K, Takahashi H, Saito Y (1988) Zeol 8:284
Suzuki M, Tsutsumi K, Takahashi H, Saito Y (1988) Zeol 8:381
Koh DJ, Chung JS, Kim YG (1991) J Chem Soc Chem Commun 849
Chung JS, Yun HG, Koh DJ, Kim YG (1993) J Mol Catal 79:199
Homeyer ST, Sachtler WMH (1989) J Catal 118:266
Feeley JS, Sachtler WMH (1991) J Catal 131:573
Zhang Z, Zhang YD, Hines WA, Budnick JI, Sachtler WMH (1992) J Am Chem Soc 114:4834
Ryoo R, Cho SJ, Pak CH, Kim JG, Ihm SK, Lee JY (1992) J Am Chem Soc 114:76
de Graaf J, van Dillen AJ, de Jong KP, Koningsberger DC (2001) J Catal 203:307
Guczi L, Beck A, Horva′th A, Horva′th D (2002) Top Catal 19:157
Sun T, Seff K (1994) Chem Rev 94:857
Seidel A, Loos J, Boddenverg B (1999) J Mater Chem 9:2495
Farzaneh F, Oskooie MK, Nejad M (1989) J Sci Ir 1:23
Murat M, Amokrane A, Bastide JP, Montanaro L (1992) Clay Mine 27:119
Chandrasekhar S, Pramada PN (1999) J Por Mater 6:283
Chang HL, Shih WH (2000) Ind Eng Chem Res 39:4185
Rayalu S, Meshram SU, Hasan MZ (2000) J Hazard Mater 77:123
Querol X, Moreno N, Umaña JC, Alastuey A, Hernández E, López-Soler A, Plana F (2002) Int J Coal Geo 50:413
Srinivasan A, Grutzeck MW (1999) Environ Sci Technol 33:1464
Ojha K, Pradhan NC, Samanta AN (2004) Bull Mater Sci 27:555
Fotovat F, Kazemian H, Kazemeini M (2008) Mater Res Bull (in press)
Ginter M, Bell AT, Radke CJ (1992) In synthesis of microporous materials, vol 1. Van Nosstrand Reinhord, New York
Tang Q, Wang Y, Zhang Q, Wan H (2003) Catal Commun 4:253
Tang Q, Zhang Q, Wang P, Wang Y, Wan H (2004) Chem Mater 16:1967
Ravishankar R, Li MM, Borgna A (2005) Catal Today 106:149
Sun S, Tsubaki N, Fujimoto K (2000) Appl Catal A 202:121
Boot LA, Kerkhoffs MHJV, van Dillen AJ, Geus JW, van Buren FR, van der Linden BTh (1996) Appl Catal A 137:69
Panpranot J, Goodwing JG Jr, Sayari A (2002) Catal Today 77:269
Jacobs G, Das TK, Zhang Y, Li J, Racoillet G, Davis BH (2002) Appl Catal A 233:263
Iglesia E, Soled SL, Fiato RA (1992) J Catal 137:212
Reuel RC, Bartholomew CH (1984) J Catal 85:78
Iglesia E (1997) Appl Catal A 161:59
Acknowledgements
The authors are expressing their outer most gratitude to Prof. A. A. Mirzaei for his kind assistance and discussion. In addition, they would like to express their thankfulness to the NSTRI, Tehran, Iran for their partial financial support of this project.
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Fotovat, F., Kazemeini, M. & Kazemian, H. Novel Utilization of Zeolited Fly Ash Hosting Cobalt Nanoparticles as a Catalyst Applied to the Fischer–Tropsch Synthesis. Catal Lett 127, 204–212 (2009). https://doi.org/10.1007/s10562-008-9671-6
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DOI: https://doi.org/10.1007/s10562-008-9671-6